Bioremediation Making using of Magnesium Peroxide / Calcium
Peroxide
Through bioremediation, soil lightly contaminated with petroleum
hydrocarbons is inoculated with a nutrient and an engineered bacteria
that combine to break down the contaminants.
The bacteria access the nutrients, which have attached to the hydrocarbons,
and quickly and thoroughly degrade the contaminants. The average time
needed to reduce contaminants to acceptable levels through bioremediation
is approximately 7 to 14 days. The bioremediation process provides substantial
cost savings when compared to thermal desorption or chemical fixation,
and is typically used on soil with lower levels of contaminants. Materials
treated through bioremediation are typically beneficially re-used as
fill material.
Biological stimulants are often used to enhance the natural attenuation
of environmental contaminants. Bioremediation products are commercially
used to attenuate such contaminants as fuel
hydrocarbon constituents and organic solvents that may bebiologically
transformed or immobilized under aerobic conditions. The dissolved oxygen
released from such products transforms/immobilizes the contaminants.
For this reason, a slow dissolved oxygen release is preferred to increase
contact with the contaminants dissolved in groundwater or adsorbed onto
the formation matrix. A fast release is ineffective when trying to remove
the contaminants. For example,
magnesium
peroxide /
calcium
peroxide is a potential stimulant for contaminant attenuation. However,
upon hydration these peroxides tend to disassociate rapidly. In fact,
magnesium/calcium peroxide can release their entire dissolved oxygen
load within afew weeks of hydration. For optimum use,
such stimulants must release dissolved oxygen slowly over a longer period
of time, on the order of months and not weeks. There are other compounds,
such as MgO
2, CaO
2 , that slowly release oxygen
when chemically bonded with phosphate. This release of oxygen is a chemical
process. Again, if the oxygen is released too fast, the compound is
useless as a bioremediation product. While chemically-bonded products
can solve the time-releasing problem, such compounds can be costly to
manufacture and use in large amounts. Magnesium Peroxide have the active
oxygen level as 10% commercially but Calcium Peroxide provide active
oxygen level as 16%.